謝文磊 教授

發布時間:2021-06-06 11:39:42 作者: 院辦
  • 謝文磊,博士,二級教授,博士研究生導師,河南工業大學化學化工學院院長。蘭州大學化學系有機化學專業本科畢業,獲學士學位;蘭州大學化學系物理化學專業碩士研究生畢業,獲碩士學位;2006年天津大學化工學院應用化學專業博士研究生畢業,獲博士學位。為中國化工學會精細化工專業委員會委員,《Advances in Chemical Engineering and Science》、《精細化工》、《食品安全質量檢測學報》編委會委員,國務院政府特殊津貼專家,河南省省管優秀專家,河南省科技創新杰出人才,首批河南省政府特殊津貼專家,河南省高等學校創新人才,河南省農副產品資源高效利用科技創新團隊負責人,河南省化工學會理事, 河南省高校生物質利用科技創新團隊負責人,河南省高校化學化工教學指導委員會委員,河南省工程碩士專業學位教育指導委員會會委員, 河南省高校青年骨干教師,河南省教育廳學術技術帶頭人,河南省生物質資源化工重點實驗室學術帶頭人。連續入選Elsevier2014年、2015年、2016年、2017年、2018年、2019年和2020年中國高被引學者榜單,I&ECR 2019年度影響力學者,Energy & Fuels 2014年度影響力學者, 入選全球前2%頂尖科學家榜單。為國家重點研發計劃和國家自然科學基金項目評審專家。主持省部以上項目17項,參與完成一項國家重點科技攻關項目和河南省重大科技攻關項目研究。近年來,主持國家自然科學基金面上項目4項,主持河南省科技創新杰出人才項目等6項。發表學術論文231篇,其中SCI論文108篇,以第一或通訊作者在國際主流期刊發表SCI論文86篇,14篇論文(均為第一作者)為ESI高被引論文(本領域全球前1%)。在科學出版社和化工出版社出版《糧油化工產品化學與工藝學》(主編)、《天然化工原料及產品手冊》(主編)等專著或教材7部,參與編纂《中國化工產品大全》和《生物化工產品》(任副主編)等工具書。獲得河南省科技進步獎等獎勵六項,申請和授權國家發明專利13件。

  • 學術榮譽或任職

  • 國務院政府特殊津貼專家

  • 河南省優秀專家

  • 首批河南省政府特殊津貼專家

  • 河南省科技創新團隊負責人

  • 河南省科技創新杰出人才

  • 河南省高等學校創新人才

  • 河南省農副產品資源高效利用創新型科技團隊

  • 河南省高校生物質利用科技創新團隊負責人

  • Advances in Chemical Engineering and Science》編委

  • 中國化工學會精細化工專業委員會委員

  • 中文核心期刊《精細化工》雜志編委會委員

  • 中國科技核心期刊《食品安全質量檢測學報》編委會委員

  • 河南省工程碩士教學指導委員會委員

  • 河南省化學會常務理事。

  • 河南省化工學會理事

  • 河南省高校青年骨干教師

  • 河南省教育廳學術技術帶頭人

  • 河南省化學化工教學指導委員會委員

  • 河南省生物質資源化工重點實驗室學術帶頭人。

  • 主持的主要科研項目

  • 1.謝文磊(主持).磁性金屬-有機骨架復合材料功能化構造及催化油脂酯交換性能調控機制,國家自然科學基金面上項目,經費70萬,2018年-2021年,編號:21776062.

  • 2.謝文磊(主持).多孔材料負載離子液體的功能化設計及對油脂酯交換催化作用,國家自然科學基金面上項目,經費88萬,2015年-2018年,編號:21476062.

  • 3.謝文磊(主持).油脂酯-酯交換多相堿催化劑的可控構造及其催化作用本質,國家自然科學基金面上項目,經費82萬,2013年-2015年,編號:21276066.

  • 4.謝文磊(主持).生物油脂酯交換中雙功能復合氧化物多相催化劑的研究,國家自然科學基金面上項目,經費36萬,2011年-2013年,編號:21076062.

  • 5.謝文磊(主持).多尺度功能化表面材料制備及催化性能研究.河南省科技創新杰出人才項目,經費50萬,編號:144200510006.

  • 6.謝文磊(主持).農副產品資源高效利用.河南省科技創新團隊項目編號: CXTD20160496.

  • 7.謝文磊(主持).生物質資源利用,河南省高校科技創新團隊項目,2012-2015年,經費60萬,編號:2012IRTSTHN009.

  • 8.謝文磊(主持).生物柴油生產中催化劑的活性和穩定性研究.河南省高校創新人才項目,經費40萬,編號:2009HASTIT024.

  • 9.謝文磊(主持). 多尺度多孔納米復合材料的功能化設計及催化生物油脂酯交換機制. 河南省高等學校重點科研項目計劃基礎研究專項,經費30萬,編號:19zx002.

  • 10.謝文磊(主持).先進催化材料的功能化設計及在質構化油脂食品生產中應用,河南省屬高校基本科研業務費專項資金.

  • 近年來代表性論著(第一和通訊作者SCI論文)

  • 1. Xie, Wenlei; Peng Hong; Chen Ligong. Transesterification of soybean Oil catalyzed by potassium loaded on alumina as a solid-base catalyst. Applied Catalysis A General,2006,300:67–74.

  • 2. Xie, Wenlei; Peng, Hong; Chen, Ligong. Calcined Mg–Al hydrotalcites as solid base catalysts for methanolysis of soybean oil. Journal of Molecular Catalysis A Chemical,2006,246:24–32.

  • 3. Xie, Wenlei; Li Haitao. Alumina-supported potassium iodide as a heterogeneous catalyst for biodiesel production from soybean oil.Journal of Molecular Catalysis A Chemical,2006,255:1–9.

  • 4. Xie Wenlei, Huang Xiaoming. Synthesis of Biodiesel from Soybean Oil using Heterogeneous KF/ZnO Catalyst.Catalysis Letters,2006,107:53-59.

  • 5. Xie, Wenlei; Huang, Xiaoming; Li, Haitao. Soybean oil methyl esters preparation using NaX zeolites loaded with KOH as a heterogeneous catalyst.Bioresource Technology, 2007, 98(4):936–939.

  • 6. Yang, Zhenqiang; Xie, Wenlei*. Soybean oil transesterification over zinc oxide modified with alkali earth metals.Fuel Processing Technology,2007, 88(6):631–638.

  • 7. Xie, Wenlei; Yang, Zhenqiang; Chun, Hong. Catalytic Properties of Lithium-Doped ZnO Catalysts Used for Biodiesel Preparations.Industrial & Engineering Chemistry, 2007, 46(24):7942-7949.

  • 8. Xie, Wenlei; Ma, Ning. Immobilized Lipase on Fe3O4 Nanoparticles as Biocatalyst for Biodiesel Production.Energy Fuels,2009,23(3):1347-1353.

  • 9. Xie, Wenlei; Ma, Ning. Enzymatic transesterification of soybean oil by using immobilized lipase on magnetic nano-particles.Biomass & Bioenergy,2010, 34(6):890–896.

  • 10. Li, Haitao; Xie, Wenlei*. Transesterification of Soybean Oil to Biodiesel with Zn/I2 Catalyst.Catalysis Letters,2006,107(1-2):25-30.

  • 11. Xie, Wenlei; Wang, Hongyan; Li, Hui. Silica-Supported Tin Oxides as Heterogeneous Acid Catalysts for Transesterification of Soybean Oil with Methanol.Industrial & Engineering Chemistry,2011,51,25-231

  • 12. Xie, Weilei; Yang, Zhenqiang. Ba–ZnO catalysts for soybean oil transesterification. Catalysis Letters,2007,117(3-4):159-165.

  • 13. Xie, Wenlei; Li, Haitao. Hydroxyl content and refractive index determinations on transesterified soybean oil.Journal of the American Oil Chemists Society, 2006, 83(10):869-872.

  • 14. Xie, Wenlei; Wang, Jianlong. Immobilized lipase on magnetic chitosan microspheres for transesterification of soybean oil.Biomass & Bioenergy,2012, 36(328):373–380.

  • 15. Wang, Yingbin, Xie, Wenlei*. Synthesis of cationic starch with a high degree of substitution in an ioni liquid. Carbohydrate Polymers,2010,80:1172–1177.

  • 16. Xie, Wenlei; Zhao, Liangliang.Production of biodiesel by transesterification of soybean oil using calcium supported tin oxides as heterogeneous catalysts.Energy Conversion and Management.2013,76,55–62.

  • 17. Xie Wenlei, Liangliang Zhao. Heterogeneous CaO-MoO3-SBA-15 catalysts for biodiesel production from soybean oil.Energy Conversion & Management,2014, 79(3):34–42.

  • 18. Xie, Wenlei; Shao, Li; Liu, Yawei. Synthesis of Starch Esters in Ionic Liquids. Journal of Applied Polymer Science,2010,116(1):218-224.

  • 19. Li, Hui; Xie, Wenlei*. Fatty Acid Methyl Ester Synthesis over Fe3+-Vanadyl Phosphate Catalysts.Journal of the American Oil Chemists Society,2008, 85(7):655-662.

  • 20. Xie, Wenlei; Yang, Dong. Transesterification of soybean oil over WO3 supported on AlPO4 as a solid acid catalyst. Bioresource Technology,2012,119(7):60–65.

  • 21. Xie, Wenlei; Wang, Tao.Biodiesel production from soybean oil transesterification using tin oxide-supported WO3 catalysts.Fuel Processing Technology, 2013,109(9):150–155.

  • 22. Xie, Wenlei; Yang, Dong. Silica-bonded N-propyl sulfamic acid used as a heterogeneous catalyst for transesterification of soybean oil with methanol. Bioresource Technology,2011,102(20),9818-9822.

  • 23. Xie, Wenlei; Shao, Li. Phosphorylation of Corn Starch in an Ionic Liquid.Starch/Starke.2009,61(12):702–708.

  • 24. Xie, Wenlei; Liu, Yawei; Chun, Hong. Biodiesel Preparation from Soybean Oil by Using a Heterogeneous CaxMg1-xO2 Catalyst.Catalysis Letters,2012, 142(3):352-359.

  • 25. Xie, Wenlei; Wang, Yingbin. Synthesis of high fatty acid starch esters with 1-butyl-3-methylimidazolium chloride as a reaction medium. Starch/Starke, 2011, 63(4):190–197.

  • 26. Xie, Wenlei; Wang, Jianlong.Enzymatic Production of Biodiesel from Soybean Oil by Using Immobilized Lipase on Fe3O4/Poly(styrene-methacrylic acid) Magnetic Microsphere as a Biocatalyst.Energy Fuels,2014,28(4),2624–2631

  • 27. Xie, Wenlei; Fan, Mingliang. Biodiesel production by transesterification using tetraalkylammonium hydroxides immobilized onto SBA-15 as a solid catalyst. Chemical Engineering Journal,2014,239(1):60–67.

  • 28. Xie, Wenlei, Zhang,Yanxian; Liu, Yawei. Homogenous carboxymethylation of starch using 1-butyl-3-methylimidazolium chloride ionic liquid medium as a solvent. Carbohydrate Polymers,2011,85(4):792–797.

  • 29. Xie, Wenlei; Fan, Mingliang.Immobilization of tetramethylguanidine on mesoporous SBA-15 silica: A heterogeneous base catalyst for transesterification of soybean oil.Bioresource Technology.2013,139: 388–392.

  • 30. Xie, Wenlei; Ji, Junmin; Wang, Hongyan. Impact of surfactant type, pH and antioxidants on the oxidation of methyl linoleate in micellar solutions.Food Research International,2007,40(10):1270–1275.

  • 31. Xie, Wenlei; Qi, Cong. Interesterification of Soybean Oil and Lard Blends Catalyzed by SBA-15-pr-NR3OH as a Heterogeneous Base Catalyst.Journal of Agricultural and Food chemistry,2013,61(14):3373-3381.

  • 32. Xie, Wenlei; Qi, Cong; Wang, Hongyan; et al. Phenylsulfonic acid functionalized mesoporous SBA-15 silica: A heterogeneous catalyst for removal of free fatty acids in vegetable oil.Fuel Processing Technology,2014,119(1):98–104.

  • 33. Xie, Wenlei; Zhao, Liangliang. Aminopropylsilica as an environmentally friendly and reusable catalyst for biodiesel production from soybean oil.Fuel, 2013:1106–1110.

  • 34. Xie, Wenlei; Ji Junming. Antioxidant activities of vitamins E and C in a novel liposome system. Journal of Food Biochemistry.2008,32 (6):766-781.

  • 35. Xie, Wenlei; Hu, Libing, Yang, Xinli. Basic Ionic Liquid Supported on Mesoporous SBA-15 Silica as an Efficient Heterogeneous Catalyst for Biodiesel Production. Industrial & Engineering Chemistry Research, 2015, 54(5):1505-1512.

  • 36. Xie, Wenlei; Chen, Jing. Heterogeneous interesterification of triacylglycerols catalyzed by using potassium-doped alumina as a solid catalyst.Journal of Agricultural & Food Chemistry, 2014, 62(43),10414-10421

  • 37. Zang, Xuezhen; Xie, Wenlei*. Enzymatic Interesterification of Soybean Oil and Methyl Stearate Blends Using Lipase Immobilized on Magnetic Fe3O4/SBA-15 Composites as a Biocatalyst. Journal of oleo science,2014,63(10):1027-1034.

  • 38. Xie, Wenlei, Qi C. Preparation of Low Calorie Structured Lipids Catalyzed by 1,5,7-Triazabicyclo[4.4.0]dec-5-ene(TBD)-functionalized Mesoporous SBA-15 Silica in a Heterogeneous Manner.Journal of Agricultural & Food Chemistry, 2014,62(15):3348-3355.

  • 39. Xie, Wenlei; Yang, Xinli; Fan, Mingliang. Novel solid base catalyst for biodiesel production: Mesoporous SBA-15 silica immobilized with 1,3-dicyclohexyl-2-octylguanidine. Renewable Energy,2015,80:230–237.

  • 40.Xie, Wenlei; Yang, Xinli; Zang, Xuezhen. Interesterification of soybean oil and methyl stearate catalyzed by guanidine-functionalized SBA-15 silica. Journal of the American Oil Chemists Society,2015,92:915-925

  • 41.Xie, Wenlei; Zang Xuezhen. Immobilized lipase on core-shell structured Fe3O4-MCM-41 nanocomposites as a magnetically recyclable biocatalyst for interesterification of soybean oil and lard.Food Chemistry,2016,194:1283-1292.

  • 42. Xie, Wenlei; Zhang Chi. Propylsulfonic and arenesulfonic functionalized SBA-15 silica as an efficient and reusable catalyst for the acidolysis of soybean oil with medium-chain fatty acids.Food Chemistry,2016,211:74-82.

  • 43. Xie, Wenlei; Hu Pengtao. Production of structured lipids containing medium-chain fatty acids by soybean oil acidolysis using SBA-15-pr-NH2–HPW catalyst in a heterogeneous manner.Organic Process Research & Development,2016,20: 637-645.

  • 44. Xie, Wenlei; Hu Libing.Biguanide-functionalized mesoporous SBA-15 silica as an efficient solid catalyst for interesterification of vegetable oils.Food chemistry,2016,197:92-99.

  • 45. Xie, Wenlei; Hu Libing.Mesoporous SBA-15 silica-supported diisopropylguanidine: an efficient solid catalyst for interesterification of soybean oil with methyl octanoate or methyl decanoate.Journal of Oleo Science,2016,65: 803-813.

  • 46. Xie, Wenlei;Yang Xinli;Hu Pengtao. Cs2.5H0.5PW12O40 encapsulated in metal–organic framework UiO-66 as heterogeneous catalysts for acidolysis of soybean oil. Catalysis Letters,2017,47:2772-2782.

  • 47. Xie, Wenlei, Han Yuxiang, Tai Shuangna. Biodiesel production using biguanide-functionalized hydroxyapatite-encapsulated-γ-Fe2O3 nanoparticles.Fuel,2017,210:83-90.

  • 48.Xie, Wenlei; Zang Xuezhen. Covalent immobilization of lipase onto aminopropyl-functionalized hydroxyapatite-encapsulated-γ-Fe2O3 nanoparticles: a magnetic biocatalyst for interesterification of soybean oil.Food Chemistry,2017,227:397-403.

  • 49.Xie, Wenlei;Huang Mengyun.Immobilization of Candida rugosa lipase onto graphene oxide Fe3O4 nanocomposite: Characterization and application for biodiesel production.Energy Conversion and Management,2018,159:42-53.

  • 50. Xie, Wenlei; Zang Xuezhen. Lipase immobilized on ionic liquid-functionalized magnetic silica composites as a magnetic biocatalyst for production of trans-free plastic fats.Food Chemistry,2018,257:15-22.

  • 51. Xie, Wenlei, Zhang Chi, Wang Hongyan. Polymeric Acidic Ionic Liquid‐Functionalized SBA‐15 as a Solid Catalyst for Production of Low‐Calorie Structured Lipids. Journal of the American Oil Chemists' Society,2018,95: 1549-1559.

  • 52. Xie, Wenlei, Zhang Chi. Production of medium-chain structured lipids using dual acidic ionic liquids supported on Fe3O4@SiO2 composites as magnetically recyclable catalysts.LWT- Food science and Technology, 2018,93: 71-78.

  • 53. Xie, Wenlei, Wan Fei. Basic ionic liquid functionalized magnetically responsive Fe3O4@ HKUST-1 composites used for biodiesel production.Fuel,2018,220: 248-256.

  • 54. Xie, Wenlei, Han Yuxiang, Wang Hongyan. Magnetic Fe3O4/MCM-41 composite-supported sodium silicate as heterogeneous catalysts for biodiesel production. Renewable Energy, 2018,125: 675-681.

  • 55. Xie, Wenlei, Wan Fei. Biodiesel Production from Acidic Oils Using Polyoxometalate-Based Sulfonated Ionic Liquids Functionalized Metal–Organic Frameworks. Catalysis Letters,2019,149,2916-2929.

  • 56. Xie, Wenlei, Wan Fei. Immobilization of polyoxometalate-based sulfonated ionic liquids on UiO-66-2COOH metal-organic frameworks for biodiesel production via one-pot transesterification-esterification of acidic vegetable oils. Chemical Engineering Journal 20419,365: 40-50.

  • 57.Xie, Wenlei, Wang Hao. Immobilized polymeric sulfonated ionic liquid on core-shell structured Fe3O4/SiO2 composites: A magnetically recyclable catalyst for simultaneous transesterification and esterifications of low-cost oils to biodiesel.Renewable Energy,2020,145,1709-1719.

  • 58.Xie, Wenlei, WanFei.Guanidine post-functionalized crystalline ZIF-90 frameworks as a promising recyclable catalyst for the production of biodiesel via soybean oil transesterification. Energy Conversion and Management, 2019,198:111922.

  • 59.Ji, Junmin, Xie Wenlei*. Detoxification of Aflatoxin B1 by magnetic graphene composite adsorbents from contaminated oils.Journal of hazardous materials,2020,381:120915.

  • 60.Xie, Wenlei;Gao, Chunli;Wang, Hongyan.Biodiesel production from low-quality oils using heterogeneous cesium salts of vanadium-substituted polyoxometalate acid Catalyst. Catalysts,2020,10(9):1060.

  • 61.Xie, Wenlei;Wang, Hao,Synthesis of heterogenized polyoxometalate-based ionic liquids with Bronsted-Lewis acid sites: A magnetically recyclable catalyst for biodiesel production from low-quality oils.Journal of Industrial and Engineering Chemistry. 2020, 87, 162-172.

  • 62.Xie, Wenlei;Huang, Mengyun,Fabrication of immobilized Candida rugosa lipase on magnetic Fe3O4-poly(glycidyl methacrylate-co-methacrylic acid) composite as an efficient and recyclable biocatalyst for enzymatic production of biodiesel. Renewable Energy, 2020,158, 474-486.

  • 63.Ji, Junmin;Xie, Wenlei*,Removal of aflatoxin B-1 from contaminated peanut oils using magnetic attapulgite, Food Chemistry, 2021, 339, 128072.

  • 64.Xie, Wenlei;Gao, Chunli;Li, Jiangbo,Sustainable biodiesel production from low-quantity oils utilizing H6PV3MoW8O40 supported on magnetic Fe3O4/ZIF-8 composites. Renewable Energy, 2021,168, ? 927-937.

  • 65.Xie, Wenlei;Wang, Hao.Grafting copolymerization of dual acidic ionic liquid on core-shell structured magnetic silica: A magnetically recyclable Bronsted acid catalyst for biodiesel production by one-pot transformation of low-quality oils. Fuel.2021,283, 118893.

  • 66.Xie, Wenlei;Xiong, Yunfei, Wang, Hongyan. Fe3O4-poly(AGE-DVB-GMA) composites immobilized with guanidine as a magnetically recyclable catalyst for enhanced biodiesel production. Renewable Energy, 2021,174, 758-768.

  • 出版的著作

  • [1]謝文磊. 糧油化工產品化學與工藝學.科學出版社.2011年.

  • [2]謝文磊. 天然化工原料及產品手冊.化學工業出版社.2010年.

  • [3]謝文磊. 生物化工產品.化學工業出版社.2008年.

  • [4]謝文磊. 化工加工技術.化學工業出版社.2005年.

  • [5]謝文磊(專題負責人)中國化工產品大全. 化學工業出版社.2004年.

  • 已完成的主要科研項目

  • 1.水難溶型維生素B3產品的研制.國家重點科技攻關項目.

  • 2.稀土配位化合物的可控模板法制備及電磁性能研究.國家自然科學基金面上項目.

  • 3.食品安全重大專項.河南省重大科技攻關項目.

  • 4.解脂假絲酵母胞外脂肪酶的提純與性能研究.部科技攻關項目.

  • 5.磷脂與環糊精包結化合物的研究.河南省重點科技攻關項目.

  • 6.固體堿催化油脂酯交換及本征動力學.河南省高校骨干教師項目.

  • 7.維生素C高級脂肪酸酯的酯交換合成技術.河南省重點科技攻關項目.

  • 8.用菜籽粕制備復合氨基酸及脂肪酰氨基酸.河南省重點科技攻關項目.

  • 9.生物柴油生產中催化劑的活性和穩定性研究.河南省高校創新人才項目

  • 近年的發明專利

  • 1.楊新麗;李浩博;曹曉雨;謝文磊;劉洋;戴維林.一種用于合成戊二醛的金屬-有機骨架固載氧化鎢催化劑及其生產方法-CN201410665534.6.

  • 2.楊新麗;劉洋;曹曉雨;謝文磊;李浩博;戴維林.一種用于合成戊二醛的金屬-有機骨架固載雜多酸催化劑及其生產方法-CN201410662264.3.

  • 3.謝文磊;臧雪珍;張弛;王宏雁.磁性核-殼型離子液體固定化脂肪酶的制備方法及在食用油脂加工中的應用-CN201510759404.3.

  • 4.謝文磊;張弛;王宏雁.中長鏈脂肪酸油脂的制備方法-CN201510606202.5.

  • 5.謝文磊;張弛;王宏雁.高疏水性耐高溫固體酸催化劑-CN201510607646.0.

  • 6.謝文磊;臧雪珍;張弛;王宏雁.一種磁性羥基磷灰石固定化脂肪酶的制備方法及在食用油脂加工中的應用-CN201510759403.9.

  • 7.謝文磊;韓玉香;王宏雁.一種固載二甲基雙胍催化劑的制備方法-CN201610205390.5.

  • 8.謝文磊;韓玉香;王宏雁.固載二甲基雙胍的磁性固體堿催化劑的制備方法-CN201610203722.6.

  • 9.謝文磊;胡朋濤;王宏雁.固載化磷鎢酸銫鹽催化劑的制備方法及應用-CN201610366847.0

  • 10.謝文磊;張弛;王宏雁.SBA?15固載聚合酸性離子液體催化劑--CN201611110377.8.

  • 獲得的省部以上科技獎勵

  • 1.謝文磊等.生物油脂酯交換固體催化劑的創制及作用機制.河南省科技進步貳等獎,2017年.

  • 2.謝文磊等.用菜籽粕制備復合氨基酸及脂肪酰氨基酸. 河南省科技進步叁等獎. 2005年.

  • 3.謝文磊等.生物油脂酯交換固體催化劑的創制及作用機制.河南省教育廳科技成果壹等獎.2016年.

  • 4.謝文磊等.飼料添加劑磷酸氫鈣生產工藝研究. 河南省優秀論文二等獎.

  • 5.謝文磊等.丙烯氰在木薯淀粉上接枝共聚研究.河南省優秀論文二等獎.

  • 6.謝文磊等.水解氨基酸微量元素絡合物飼料添加劑的合成工藝研究.河南省優秀論文二等獎.

  • 7.謝文磊等.由脫脂豆粕合成N-月桂酰基氨基酸基表面活性劑.河南省優秀論文二等獎.



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