曹曉雨

發布時間:2019-09-21 16:34:22 作者:

曹曉雨,男,1979年9月生,九三學社社員,博士,教授,博士生導師。1997年–2001年,在河南師范大學化學與環境科學學院學習,獲工學學士學位;2001年–2006年,在武漢大學化學與分子科學學院物理化學專業(電化學方向)碩博連讀,獲理學博士學位;2006至今,在河南工業大學化學化工學院從事物理化學的教學和電化學能量儲存與轉換方面的研究工作。現為鄭州市高比能化學電源材料重點實驗室主任、中國化學會會員、韓國電子材料研究協會會員、河南省化學與材料青年學者聯合會理事、多個國際SCI收錄期刊長期審稿人。

近年來,主持國家自然科學基金項目、河南省重點科技攻關計劃項目、河南省科技開放合作計劃項目、河南省高校科技創新團隊支持計劃項目、河南省高校科技創新人才支持計劃項目、鄭州市創新型科技領軍人才項目及河南省高等學校青年骨干教師資助計劃項目;主持了4項河南省科技成果鑒定(均為國內領先水平),其中2項成果獲河南省教育廳科技成果壹等獎;在ACS Applied Materials & Interfaces、Chemical Engineering Journal、Electrochimica Acta等國際刊物上發表SCI收錄論文70余篇,其中獲河南省自然科學優秀學術論文壹等獎5項;編寫學術著作2部;獲授權國家發明專利4項。榮獲了河南省學術技術帶頭人、河南省教育廳學術技術帶頭人、鄭州市青年科技專家(鄭州市青年科技獎)、河南歷史大事年編″時代英模″、河南省優秀碩士學位論文指導教師、鄭州市科技創新工作先進個人、河南工業大學畢業設計(論文)優秀指導教師、河南工業大學優秀教師、河南工業大學就業創業工作優秀指導教師、河南工業大學畢業生┄″我心目中最優秀的老師″等榮譽稱號。

主持的科研項目:

1. NSFC-河南聯合基金培育項目,U1704142,基于釩酸銀和釩酸銅放電特性Li4Ti5O12復合物材料的制備及電化學性能改善研究,2018.01–2020.12,50萬元,在研,主持。

2.河南省科技開放合作計劃項目,132106000075,磷酸釩鋰復合物的設計合成及性能研究,2013.01–2015.12,45萬元,已結項,主持。

3.河南省重點科技攻關計劃項目,122102210114,脫鋰態鋰電池正極材料的制備工藝研究,2012.01–2014.12,20萬元,已結項,主持。

4.河南省基礎與前沿技術研究計劃項目,092300410117,心臟起搏器電池電極材料Ag2V4O11的循環性能研究,2009.01–2011.12,已完成,主持。

5.河南省高校科技創新團隊支持計劃,17IRTSTHN003,清潔能源高效轉化,

2017.01–2019.12,100萬元,在研,負責人。

6.河南省高校科技創新人才支持計劃,2011HASTIT017,鋰離子電池新型復

合物電極材料的設計、合成及電化學性能研究,2011.01–2013.12,40萬元,已結項,主持。

7.鄭州市創新型科技領軍人才項目,131PLJRC652,動力型復合鋰離子電池電極材料研究,2013.01–2015.12,50萬元,已完成,主持。

8.河南省高等學校青年骨干教師計劃項目,2009GGJS-059,表面包覆LiV3O8作高比能鋰二次電池正極材料的電化學循環性能改善研究,2009.01–2011.12,4萬元,已完成,主持。

9.鄭州市科技攻關計劃項目,083SGYG25121-3,鋰離子電池關鍵材料的研究與開發,2008.01–2010.12,4萬元,已完成,主持。

10.河南工業大學″省屬高校基本科研業務費專項資金″項目,2014YWQN03,

離子摻雜Li3V2(PO4)3正極材料的合成及電化學性能研究,2014.01–2016.12,5萬元,已結項,主持。

11.河南工業大學″省屬高校基本科研業務費專項資金″項目,2018RCJH01,高性能可逆鋰存儲負極材料的合成及電化學性能研究,2018.01–2020.12,8萬元,在研,主持。

發表的部分學術論文:

1. Limin Zhu, Wenxuan Li, Lei Wang, Lingling Xie, Qi Yang,Xiaoyu Cao*,Rod-like NaV3O8as cathode materials with high capacity and stability for sodium storage, Chemical Engineering Journal, 2019, 372, 1056–1065.

2. Lei Wang, Zehua Wang, Lingling Xie, Limin Zhu*, Xiaoyu Cao*, ZIF-67 derived N-doped Co/C nanocubes as high-performance anode materials for mithium-ion batteries,ACS Applied Materials & Interfaces, 2019, 11 (18), 16619–16628.

3.Limin Zhu, Zehua Wang, Lei Wang, Lingling Xie, Jingjing Li,Xiaoyu Cao*,ZnSe embedded in N-doped carbon nanocubes as anode materials for high-performance Li-ion batteries, Chemical Engineering Journal,2019, 364, 503–513.

4. Limin Zhu, Lingling Xie,Xiaoyu Cao*,LiV3O8/polydiphenylamine composites with significantly improved electrochemical behavior as cathode materials for rechargeable lithium batteries, ACS Applied Materials & Interfaces, 2018, 10 (13), 10909–10917.

5. Limin Zhu, Guochun Ding, Jingbou Liu, Ziqi Yu, Lingling Xie*, Xiaoyu Cao*, Graphene-wrapped poly(2,5-dihydroxy-1,4 benzoquinone-3,6-methylene) nanoflowers as low-cost and high-performance cathode materials for sodium-ion batteries,International Journal of Energy Research, 2019,DOI: 10.1002/er.4764.

6.Limin Zhu, Lingling Xie*, Chenguang Bao, Xiangyang Yan, Xiaoyu Cao*,LiNi1/3Co1/3Mn1/3O2/polypyrrole composites as cathode materials for high-performance lithium-ion batteries,International Journal of Energy Research, accepted.

7.Tianjing Wu, Chenyang Zhang, Guoqiang Zou, Jiugang Hu, Limin Zhu, Xiaoyu Cao*, Hongshuai Hou, Xiaobo Ji*,The bond evolution mechanism of covalent sulfurized carbon during electrochemical sodium storage process,Science China-Materials, 2019, 62 (8), 11271138.

8. Jingjing Li, Hongliang Wei, Peng Yu, Lifang Geng, Limin Zhu, Xiaoyu Cao*, Chunsen Liu*, Huan Pang*, A multifunctional self-healing G-PyB/KCl hydrogel: Smart conductive, rapid room-temperature phase-selective gelation, and ultrasensitive detection of alpha-fetoprotein, Chemical Communications, 2019, 55 (55), 79227925.

9. Xiaoyu Cao*, Jingbo Liu, Limin Zhu*, Lingling Xie, Polymer electrode naterials for high-performance lithium/sodium-ion batteries: A review, Energy Technology, 2019, 7(7), 1800759.

10. Xiaoyu Cao*, Qiancheng Sun, Limin Zhu*, Lingling Xie, Na3V2(PO4)3nanoparticles confined in functional carbon framework towards high-rate and ultralong-life sodium storage, Journal of Alloys and Compounds, 2019, 791,296306.

11. Xinli Yang, Chengguang Bao, Linglingxie, Limin Zhu*, Xiaoyu Cao*, Preparation of LiNi1/3Co1/3Mn1/3O2/polytriphenylamine cathode composites with enhanced electrochemical performances towards reversible lithium storage, Ceramics International, 2019, 45 (8), 97269735.

12. Tianjing Wu, Mingjun Jing, Ye Tian, Li Yang, Jiugang Hu, Xiaoyu Cao, Guoqiang Zou, Hongshuai Hou, and Xiaobo Ji*, Surface-driven energy storage behavior of dual-heteroatoms functionalized carbon material, Advanced Functional Materials, 2019, 29 (17), 1900941.

13. Wanwan Hong, Peng Ge, Yunling Jiang, Li Yang, Ye Tian, Guoqiang Zou, Xiaoyu Cao, Hongshuai Hou*, Xiaobo Ji, Yolk-shell-structured bismuth@N-doped carbon anode for lithium-ion battery with high volumetric capacity,ACS Applied Materials & Interfaces, 2019, 11 (11), 10829–10840.

14. Tianjing Wu, Mingjun Jing, Li Yang, Guoqiang Zou, Hongshuai Hou, Yang Zhang, Yu Zhang, Xiaoyu Cao, Xiaobo Ji* Controllable chain-length for covalent sulfur-carbon materials enabling stable and high-capacity sodium storage, Advanced Energy Materials,2019, 9 (9), 1803478.

15.Limin Zhu, Jingbo Liu, Ziqi Liu, Lingling Xie, Xiaoyu Cao*,Anthraquinones with ionizable sodium sulfonate groups as renewable cathode materials for sodium-ion batteries, ChemElectroChem, 2019, 6 (3), 787792.

16. Peng Ge, Sijie Li, Laiqiang Xu, Kangyu Zou, Xu Gao, Xiaoyu Cao, Guoqiang Zou, Hongshuai Hou, Xiaobo Ji*Hierarchical hollow-microsphere metal-selenide@carboncomposites with rational surface engineering for advancedsodium storage,Advanced Energy Materials, 2019, 9 (1), 1803035.

17. Lingling Xie, Peng Ge, Limin Zhu, Xiaoyu Cao*, Stabilization of LiV3O8rod-like structure by protective Mg3(PO4)2layer for advanced lithium storage cathodes, Energy Technology, 2018, 6 (12), 2479–2487.

18. Peng Ge, Hongshuai Hou, Xiaoyu Cao, Sijie Li, Ganggang Zhao, Tianxiao Guo, Chao Wang, Xiaobo Ji*, Multidimensional evolution of carbon structures underpinned by temperature-induced intermediate of chloride for sodium-ion batteries, Advance Science,2018, 5 (6), 1800080.

19. Xiaoyu Cao*,Qi Yang, Limin Zhu*,Lingling Xie,NaV3O8with superior rate capability and cycle stability as cathode materials forsodium ion batteries,Ionics, 2018, 24(3), 943–949.

20.Ganggang Zhao, Guoqiang Zou, Hongshuai Hou*, Peng Ge,Xiaoyu Cao,Xiaobo Ji,Sulfur-doped carbon employing biomass-activated carbon as a carrier with enhanced sodium storage behavior,Journal of Materials Chemistry A, 2017, 5 (46), 24353–24360.

21.Guoqiang Zou, Hongshuai Hou*,Xiaoyu Cao,Peng Ge,Ganggang Zhao, Dulin Yin, Xiaobo Ji,3D hollow porous carbon microspheres derived from Mn-MOFs and their electrochemical behavior for sodium storage, Journal of Materials Chemistry A, 2017, 5 (45), 23550–23558.

22. Limin Zhu,Wenjuan Li, Ziheng Yu, Lingling Xie,Xiaoyu Cao*,Synthesis and electrochemical performances of LiV3O8/poly(3, 4-ethylenedioxythiophene) composites as cathode materials for rechargeable lithium batteries, Solid State Ionics, 2017, 310, 30–37.

23. Limin Zhu,Wenjuan Li, Lingling Xie,Xiaoyu Cao*, LiV3O8/poly(1,5-diaminoanthraquinone) composite as a high performance cathode material for rechargeable lithium batteries, Materials Letters, 2017, 206, 225–228.

24. Peng Ge,Xiaoyu Cao,Hongshuai Hou,Sijie Li,and Xiaobo Ji*, Rodlike Sb2Se3wrapped with carbon: The exploring of electrochemical properties in sodium-ion batteries, ACS Applied Materials & Interfaces, 2017, 9 (40), 34979?34989.

25.Zehua Wang, Xiaoyu Cao*, Peng Ge, Limin Zhu, Lingling Xie, Hongshuai Hou*, Xiaoqing Qiu, Xiaobo Ji,Hollow-sphere ZnSe wrapped around carbon particles as a cycle-stable and high-rate anode material for reversible Li-ion batteries, New Journal of Chemistry, 2017, 41 (14): 6693–6699.

26. Wenjuan Li, Limin Zhu*, Ziheng Yu, Lingling Xie, Xiaoyu Cao*, LiV3O8/polytriphenylamine composites with enhanced electrochemical performances as cathode materials for rechargeable lithium batteries, Materials, 2017, 10 (4): 344.

27. Xiaoyu Cao*, Lulu Mo, Limin Zhu*, Lingling Xie, Preparation and electrochemical properties of Li3V2(PO4)3-xBrx/carbon composites as cathode materials for lithium-ion batteries, Nanomaterials, 2017, 7(3): 52.

28. Xiaoyu Cao*, Jiejie Zhang, Limin Zhu, Preparation of LiV3O8/polypyrrole and their derived LiV3O8/carbon composites as cathode materials for lithium rechargeable batteries, Journal of Nanoscience and Nanotechnology, 2015, 15 (9), 7081–7086.

29. Xiaoyu Cao*, Limin Zhu, Hailian Wu, Preparation and electrochemical performances of rod-like LiV3O8/carbon composites using polyaniline as carbon source, Electronic Materials Letters,2015, 11 (4), 650–657.

30. Limin Zhu, Xiaoyu Cao*,p-Dopable poly(4-cyano)triphenylamine: A high voltage organic cathode for lithium ion batteries, Materials Letters, 2015, 150, 16–19.

31. Weixin Song, Xiaoyu Cao, Zhenping Wu, Jun Chen, Yirong Zhu, Hongshuai Hou, Qing Lan, X.B. Ji*, Investigation of the sodium ion pathway and cathode behavior in Na3V2(PO4)2F3combined via a first principles calculation, Langmuir, 2014, 30 (41), 12438–12446.

32. Weixin Song, Xiaoyu Cao, Zhengping Wu, Jun Chen, Kaili Huangfu, Xiaowen Wang, Yaliang Huang, Xiaobo Ji*, A study into the extracted ion number for NASICON structured Na3V2(PO4)3in sodium-ion batteries, Physical Chemistry Chemical Physics, 2014, 16 (33), 17681–17687.

33. Xiaoyu Cao*, Shuangqiang Chen, Guoxiu Wang*, Porous carbon particles derived from natural peanut shells as lithium ion battery anode and its electrochemical properties, Electronic Materials Letters, 2014, 10 (4), 819–826.

34. Xiaoyu Cao*, Jiejie Zhang, Rheological phase synthesis and characterization of Li3V2(PO4)3/C composites as cathode materials for lithium ion batteries, Electrochimica Acta, 2014, 129, 305–311.

35. Hongshuai Hou, Xiaoyu Cao, Yingchang. Yang, Laibing Fang, Chengchi Pan, Xuming Yang, Weixin Song, Xiaobo Ji*, NiSb alloy hollow nanospheres as anode materials for rechargeable lithium ion batteries, Chemical Communications, 2014, 50 (60), 8201–8203.

36. Lingling Xie, Yuandong Xu, Jiejie Zhang, Chengpeng Zhang, Xiaoyu Cao*, Lingbo Qu*, Rheological phase synthesis of Er-doped LiV3O8as electroactive material for a cathode of secondary lithium storage, Electronic Materials Letters, 2013, 9 (4), 549–553.

37. Lingling Xie, Xiaoyu Cao*, Lixu Zhang, Zhongxu Dai*, Lingbo Qu, Synthesis and electrochemical properties of LiV3O8/PAn composite as a cathode material for lithium secondary batteries, Electronic Materials Letters, 2013, 9 (2), 183–186.

38. Lingling Xie, Liqin You, Xiaoyu Cao*, Chaofeng Zhang, Dawei Song, Lingbo Qu, Co3(PO4)2-coated LiV3O8as positive materials for rechargeable lithium batteries, Electronic Materials Letters, 2012, 8 (4), 411–415.

39. Xiaoyu Cao*, Lingling Xie, Ruijuan Wang, A soft chemistry synthetic method for preparing LiNi0.8Co0.2O2with enhanced electrochemical performances, Journal of Solid State Electrochemistry, 2011, 15 (3), 473–478.

40. Xiaoyu Cao*, Chao Yuan, Lingling Xie, Hui Zhan, Yunhong Zhou, Low-temperature synthesis of Cu-doped Li1.2V3O8as cathode for reversible lithium storage, Ionics, 2010, 16 (1), 39–44.

41. Xiaoyu Cao, Lingling Xie, Hui Zhan*, Yunhong Zhou, Large-scale synthesis of Li1.2V3O8as a cathode material for lithium secondary battery via a soft chemistry route, Materials Research Bulletin, 2009, 44 (2): 472–477.

所獲學術成果獎勵:

1.河南省教育廳科技成果壹等獎,磷酸釩鋰復合物的設計合成及性能研究,豫教[2017]3771號,2017年,第一完成人。

2.河南省教育廳科技成果壹等獎,LiV3O8/PAn復合物正極材料的制備及電化學性能,豫教[2016]01397號,2016年,第一完成人。

3.河南省第三屆自然科學學術獎┄自然科學優秀學術論文壹等獎,Hydrogen peroxide biosensor based on hemoglobin immobilized at graphene, flower-like zinc oxide, and gold nanoparticles nanocomposite modified glassy carbon electrode,河南省人力資源與社會保障廳、河南省科學技術協會,2015年,第三完成人。

4.河南省第三屆自然科學學術獎┄自然科學優秀學術論文貳等獎,Rheological phase synthesis and characterization of Li3V2(PO4)3/C composites as cathode materials for lithium ion batteries,河南省人力資源與社會保障廳、河南省科學技術協會,2015年,第一完成人。

5.河南省第二屆自然科學學術獎┄自然科學優秀學術論文壹等獎,Preparation of ZnO-coated LiV3O8as cathode materials for rechargeable lithium batteries,河南省人力資源與社會保障廳、河南省科學技術協會,2013年,第一完成人。

6.河南省第二屆自然科學學術獎┄自然科學優秀學術論文貳等獎,Synthesis and characterization of lithium trivanadates as cathode materials for rechargeable lithium battery via a new wet chemical synthesis method,河南省人力資源與社會保障廳、河南省科學技術協會,2013年,第一完成人。

7.河南省第二屆自然科學學術獎┄自然科學優秀學術論文貳等獎,A soft chemistry synthetic method for preparing LiNi0.8Co0.2O2with enhanced electrochemical performances,河南省人力資源與社會保障廳、河南省科學技術協會,2013年,第一完成人。

8.河南省第二屆自然科學學術獎┄自然科學優秀學術論文壹等獎,Co3(PO4)2-coated LiV3O8as positive materials for rechargeable lithium batteries,河南省人力資源與社會保障廳、河南省科學技術協會,2013年,第三完成人。

9.河南省首屆自然科學學術獎┄自然科學優秀學術論文壹等獎,Low-temperature synthesis of Cu-doped Li1.2V3O8as cathode for reversible lithium storage,河南省人力資源與社會保障廳、河南省科學技術協會,2011年,第一完成人。

10.河南省首屆自然科學學術獎┄自然科學優秀學術論文壹等獎,Rheological phase synthesis and characterization of micro-sized Li4Ti5O12,河南省人力資源與社會保障廳、河南省科學技術協會,2011年,第二完成人。

11.河南省首屆自然科學學術獎┄自然科學優秀學術論文貳等獎,Large-scale synthesis of Li1.2V3O8as a cathode material for lithium secondary battery via a soft chemistry route,河南省人力資源與社會保障廳、河南省科學技術協會,2011年,第一完成人;

12.河南省首屆自然科學學術獎┄自然科學優秀學術論文貳等獎,A Novel approach to massive preparation of LiV3O8as a cathode material for lithium rechargeable battery,河南省人力資源與社會保障廳、河南省科學技術協會,2011年,第一完成人;

13.河南省第十屆自然科學優秀學術論文貳等獎,Facile preparation of Ag2V4O11nanoparticles via low-temperature molten salt synthesis method,河南省人力資源與社會保障廳、河南省科學技術廳、河南省科學技術協會,2010年,第一完成人。

聯系方式:E-mail:caoxy@haut.edu.cn

Tel: 0371-67756193

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